Late Quaternary carbonate sedimentation at the Sierra Leone Rise (eastern equatorial Atlantic Ocean)

Abstract

In the eastern equatorial Atlantic Ocean, changes in the concentration of carbonate in Late Quaternary sediments resulted from reduced production of carbonate in surface waters and increased dilution with non-carbonate sediments during glacial maxima. During glacial stages, production of carbonate in surface water (measured as its accumulation rate in shallow, undissolved cores) decreased by one half. The glacial accumulation rate of non-carbonate components increased 1.5 to 4 times over Holocene values; the greatest increases occurred in the deepest cores. Carbonate dissolution during stages 2, 3 and 4 increased the proportion of foraminiferal fragments and decreased the accumulation rate of susceptible species in the deep sites. In shallow sites, slightly increased dissolution can be detected during stage 3 while greatly increased dissolution occurred during stage 4. Bathymetric profiles of foraminiferal fragmentation and accumulation document a shoaling of the foraminiferal lysocline by 1000 m during glacial isotopic stages. We present a mass balance model of sediment accumulation for carbonate and insoluble components and from this model we estimate the rate of downslope transport and dissolution of carbonate at the Sierra Leone Rise. Our results show that during stage 4 the rate of carbonate loss to dissolution was greater than the rate observed today or during other interglacial stages. The calculated rates of dissolution for stages 2 and 3 are not significantly different from those calculated for stage 1.