Large scale synthesis of flower-like SnO2 nanostructures via a facile hydrothermal route

Abstract

Materials with hierarchical architectures often exhibit novel functional properties. In this paper, the hierarchical SnO2 flower-like architecture, consisting of numerous aggregative nanosheets was successfully synthesized via a facile hydrothermal method and subsequent calcination. The structures and morphologies of this hierarchical architecture were characterized in detail by means of powder X-ray diffraction (XRD) and field-emission scanning electron microscopy (FE-SEM). Further comparative experiments show that the sodium citrate was benefit to promote the growth of SnO2 nanosheets and accelerate the assembling of nanosheets into flower-like architecture, the PEG provided nucleation sites and made the nanoflowers grow uniformly and separated. Moreover, a possible growth mechanism of the flower-like architectures was proposed. The non-trivial behavior of flower-like SnO2 may be driven by the properties of grain boundaries.