Abstract
The wide optical band gaps of ferroelectric perovskite oxides have restricted their light absorbing capacities in the photovoltaic devices. In this work, an ultra-narrow band gap E g and wide optical absorption across the ultraviolet-visible-infrared sunlight spectrum was achieved in lanthanum and strontium atoms modified Bi(Fe, Mn)O3 perovskites by chemical substitution and defect engineering. XRD results show that the A and B site co-substituted samples are single phase. The XPS characterizations indicate the Fe ions are in the trivalent state for all the samples. The LM6 and SM6 samples exhibit an ultra-narrow band gap about 1.26 eV and 1.06 eV, respectively. The reduced E g was due to the defect states produced within the band gap, acting as a scaffold to give electrons to Fe 3d states and receive the electrons from O 2p states. Based on this research, these chemically modified BFO based perovskite could potentially extend its sunlight absorption deep into the infrared region.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
