Abstract
Abstract Two ternary lanthanide complexes [Ln(2-Br-5-MOBA)3(5,5′-DM-2,2′-DIPY)]2 (Ln = Sm(1), Eu(2); 2-Br-5-MOBA = 2-bromo-5-methoxybenzoate; 5,5′-DM-2,2′-DIPY = 5,5′-dimethyl-2,2′-bipyridine) with 2-bromo-5-methoxybenzoic acid and 5,5′-dimethyl-2,2′-bipyridine have been synthesized and characterized. The Single-crystal X-ray diffraction date show that complexes 1 and 2 are isostructural in the triclinic system, space group P 1 ¯ . Infrared spectra (IR) and X-ray powder diffraction (PXRD) further confirm that complexes 1 and 2 are isostructural. The basic structural unit forms a 1D chain through the weak C H⋯Br hydrogen bond interaction along the b-axis, and forms a 2D sheet through the π–π stacking interactions along the a-axis. The 2D sheets are further interconnected by the C H⋯O hydrogen bond interaction to assembled into a 3D supramolecular network along the c-axis. In addition, the simultaneous thermal analysis (TG, DTG and DSC) of the complexes and the FTIR spectra of the escaped gas were measured. The heat capacities of the complexes were determined by DSC in the temperature region of 258.15–393.15 K. Furthermore, the luminescence spectrum of the complexes 1 and 2 and luminescence lifetime of complex 2 were also measured.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.