Abstract
A homochiral MOF, PCN-261-NHPro, was prepared via solvothermal synthesis of Fe2CoO(CH3COO)6 with H3tcpb-NHPro. The aldol addition was selected as a model reaction for the estimation of the catalytic performance of the PCN-261-NHPro, which showed reversed diastereomeric selectivity in contrast to homogeneous catalysts.
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