Abstract
Rate constants and the ratio of rates of two available reaction channels (branching ratios) for the reactions of hydrogen and deuterium atoms with FCl, ICl, and BrF molecules were measured using a fast-flow reactor with RF discharge as source of atoms and with superheterodyne ESR spectrometer as detector. For the reaction with FCl a substantial difference was found in branching ratios when substituting hydrogen atoms with deuterium ones: ΓD+FCl/ΓH+FCl = 3.3±0.2. The results are compared with the known experimental data and theoretical calculations; in particular, the possible influence of light atom (H or D) migration in collision complex on reaction mechanism is discussed.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.