Abstract
1. The decomposition of xenon trioxide in aqueous solution proceeds via a chain mechanism over the range 1 < pH < 10 with the formation of hydrogen peroxide and XeO2 (XeO) as intermediate substances. 2. Over the range pH >10 the chain mechanism changes to an ionic mechanism involving the di-sproportionation of Xe(VI) with the formation of Xe(VIII) perxenates.
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