Abstract

1-Hexene ignition delay times were measured behind reflected shock waves for 0.1% fuel diluted in Ar between 1270 and 1700 K, at pressures between 0.2 and 1 MPa. 1-C 6H 12 ignition delay times were measured by following OH chemiluminescence emission. 1-Hexene oxidation has been investigated in the jet-stirred reactor (JSR) between 750 and 1200 K, at a pressure of 1 MPa, and 0.1% of fuel diluted in N 2. In both experimental studies, three equivalence ratios, 0.5, 1, and 1.5, were investigated. Molecular species concentration profiles were obtained by sonic probe sampling and GC analyses during 1-hexene oxidation in JSR. H 2, CO, CO 2, CH 2O, CH 4, C 2H 4, C 3H 6, 1-C 4H 8, and 1,3-C 4H 6 were the major products of 1-C 6H 12 oxidation. All the experimental data have been compared to those calculated using a detailed chemical kinetic reaction mechanism.

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