Kinetics, equilibrium data and modeling studies for the sorption of chromium by Prosopis juliflora bark carbon

Abstract

In this study, the activated carbon was prepared from Prosopis juliflora bark as a novel adsorbent. Removal of chromium (Cr) was assessed by varying the parameters like metal concentration, temperature, pH, adsorbent dose and contact time. The feasibility of the sorption was studied using Freundlich and Langmuir isotherms including linear and non-linear regression methods. In Langmuir, various forms of linearized equations were evaluated. The isotherm parameter of dimensionless separation factor (RL) was also studied. The kinetics of adsorption was studied by using Lagergren’s pseudo-first order and pseudo-second order equations and the results have shown that the adsorption process follows pseudo-second order kinetics and the adsorption process depends on both time and concentration. The mechanistic pathway of the adsorption process was evaluated with intraparticle diffusion model. The effect of heat of adsorption of the adsorbate onto the adsorbent material was determined using the thermodynamic parameters and the reusability of the adsorbent materials was ascertained with desorption studies. The adsorbent material characterization was done by using Fourier Transform Infrared Spectroscopy (FTIR), X-ray Diffraction (XRD) method and morphology of the surface of adsorbent was identified with Scanning Electron Microscope (SEM).