Kinetics and Mechanisms of Oxidation of 2D Woven C/SiC Composites: I, Experimental Approach

Abstract

The oxidation behavior of a 2D woven C/SiC composite partly protected with a SiC seal coating and heat‐treated (stabilized) at 1600°C in inert gas has been investigated through an experimental approach based on thermogravimetric analyses and optical/electron microscopy. Results of the tests, performed under flowing oxygen, have shown that the oxidation behavior of the composite material in terms of oxidation kinetics and morphological evolutions is related to the presence of thermal microcracks in the seal coating as well as in the matrix. Three different temperature domains exist. At low temperatures (<800°C), the mechanisms of reaction between carbon and oxygen control the oxidation kinetics and are associated with a uniform degradation of the carbon reinforcement. At intermediate temperatures, (between 800° and 1100°C), the oxidation kinetics are controlled by the gas‐phase diffusion through a network of microcracks in the SiC coating, resulting in a nonuniform degradation of the carbon phases. At high temperatures (>1100°C), such diffusion mechanisms are limited by sealing of the microcracks by silica; therefore, the degradation of the composite remains superficial. The study of the oxidation behavior of (i) the heat‐treated composite in a lower oxygen content environment (dry air) and (ii) the as‐processed (unstabilized) composite in dry oxygen confirms the different mechanisms proposed to explain the oxidation behavior of the composite material.