Abstract
A kinetic analysis was made of the thermal decomposition of benzoyl peroxide in polyamide in inert atmosphere. It was established that the decomposition of peroxide takes place simultaneously by monomolecular and chain mechanisms. Chain decomposition of benzoyl peroxide is induced by polymer macromolecules and the order of the reaction is 1 2 . Thermal decomposition of benzoyl peroxide in polyamide causes decomposition of polymer macromolecules. It was shown that macromolecular rupture does not involve the induced decomposition of peroxide.
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