Abstract
Aryl substituent effects upon the rate constants for the esterification of a series of arylmethanols in neat trifluoroacetic acid are in accordance with a reverse AAC2 mechanism for those substrates bearing an electron-withdrawing substituent (ρ=–0·79), whereas a reverse AAL1 mechanism is indicated for those bearing a methyl substituent.
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More From: Journal of the Chemical Society, Chemical Communications
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