Abstract
The water substitution reactions of the monocation Co(III)(H 2O) 2(salen) + [salen = N,N′-ethylene-bis(salicylideneiminate)] were studied in aqueous solution. The nucleophiles used were pyridine, thiourea, morpholine, aniline, imidazole, NCO −, HSO 3 −, S 2O 3 2−. The kinetics of mono-substitution reactions were found to be very rapid, with second order rate constants nearly independent of the nature of the incoming ligand. A comparison is made with the corresponding reactions of Co(III)hematoporphyrin and some other macrocyclic complexes.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
