Abstract
In this paper the kinetic modeling of acid-catalyzed oil-refining processes is based upon the elementary steps of carbenium-ion chemistry. This completely avoids the lumping of species and reactions practised today. A number of reasonable assumptions, the introduction of the single-event concept, the Polanyi relation and thermodynamic constraints keep the number of kinetic parameters within tractable limits. The approach is applied to the simulation of a riser reactor for the catalytic cracking of gasoil.
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