Abstract
Mass spectral and thermal studies of several aryliodine(III) dicarboxylates in a static air atmosphere have been carried out to determine their modes of decomposition. Fragmentation patterns are given and possible mechanisms are discussed. All compounds show similar thermograms and DTA profiles. Reaction orders were estimated by employing the Freeman-Carroll equation, and a kinetic analysis of the TG data was performed using the Coats-Redfern equation to determine the apparent activation energies and the pre-exponential factor of the Arrhenius equation.
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