Abstract

A mathematical model has been used to analyse the effect of phase equilibrium, conversion and kinetic factors on the rate of copolymerization, composition and molecular mass of the polymer formed during the copolymerization of ethylene with hexene-1 in solution on a highly active TiMg catalyst. An interpretation is proposed for the promoting effect observed during the copolymerization of ethylene with octene-1 and nonene-1, which was found previously in the copolymerization of ethylene with hexene-1.

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