K0.54[Co0.5Mn0.5]O2: New cathode with high power capability for potassium-ion batteries

Abstract

We propose P3-K0.54[Co0.5Mn0.5]O2, which is rationally designed as a promising cathode material for high-performance potassium-ion batteries (KIBs). Its composition adopts the use of the valence state of Mn above 3.5 + to minimize the disruptive effect of Jahn–Teller distortion in the MnO6 octahedra during the electrochemical reaction. Unlike other types of layered materials that suffer from the sluggish diffusion of large potassium ions accompanying multi-step voltage profiles, P3-K0.54[Co0.5Mn0.5]O2 delivers a high specific discharge capacity of 120.4 mAh (g-oxide)−1 with smooth charge and discharge curves. First-principles calculations predict an activation barrier energy of ∼260 meV for a large K+ diffusion, which is comparable to those observed in conventional layered cathode materials for lithium-ion batteries. As a result, even at 500 mA g−1, P3-K0.54[Co0.5Mn0.5]O2 is able to deliver a high discharge capacity of 78 mAh g−1, which is a retention of 65% versus the capacity obtained at 20 mA g−1. Combination studies using operando X-ray diffraction, the ex-situ X-ray absorption near-edge structure, and first-principles calculations elucidate the nature of the excellent potassium storage mechanism of K0.54[Co0.5Mn0.5]O2. This work provides a new insight for the development of efficient cathode materials for KIBs.