Abstract

Comparison within the title [Re6Q8X6]4-/[Re6Q8X6]3- redox series of 14 precise crystal structures of the Re6 cluster cores at different low temperatures reveals that the one-electron oxidised, open-shell (23 electron) cores undergo a Jahn-Teller distortion of their parent 24 electron octahedral cores and that D4h and D2h forms may co-exist in the solid state.

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