Abstract
Ideal gas phase isotopic partition function ratios involving both deuterium and tritium substitution for hydrogen and also heavy atom substitution in H2, H2O, H2S, H2Se, and NH3 have been calculated at a number of temperatures. The results have been least squares fitted to a five term series in powers of (300/T). Various correction factors to the harmonic approximation were considered in the calculation of the partition function ratios. It is demonstrated that the tabulated ratios can be used to calculate equilibrium constants for isotopic exchange reactions.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
