Abstract
The selective IR multiphoton decomposition of 12CF 3I in the presence of NO 2 as radical scavenger was used to obtain isotopic enrichment of 13C in a one- stage process. The 12CF 3 radicals produced by IR photolysis react with NO 2 through a fast bimolecular reaction to yield 12CF 2O together with undissociated 13CF 3I as the main carbon-containing products. The isotopic enrichment increases with the [NO 2]/[CF 3I] ratio. The results are compared with those obtained using O 2 as scavenger.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of Photochemistry & Photobiology, A: Chemistry
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
