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Abstract
High-pressure vapor−liquid phase equilibrium (P, x, y) were measured for the binary systems of nitrogen + dimethyl sulfoxide, nitrogen + N-methyl-2-pyrrolidone, and nitrogen + diethylene glycol monobutyl ether over a temperature rage between (323.15 and 393.15) K. In addition to the new data, the Soave−Redlich−Kwong, Peng−Robinson, and Patel−Teja equations of state accompanied by several types of mixing rule were also used to correlate these vapor−liquid phase behaviors. In general, the Patel−Teja equation incorporated with mixing rule-C (linear temperature-dependent combining rule for aij) yielded the best representation.
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