Abstract
The isothermal section of the phase diagram of ternary Ti–Mn–Sn system has been investigated at 770 K. The existence of new TiMnSn 4 ternary compound was established and its crystal structure was determined. TiMnSn 4 stannide crystallizes in the Mg 2Ni structure type (space group P6 222 , a=0.55537(1) nm, c=1.40326(2) nm). For the given compound the temperature dependences of electrical resistivity, differential thermopower and magnetic susceptibility were investigated. On the basis of binary Mn 3Sn, Ti 6Sn 5 and Ti 3Sn compounds the solid solutions were formed.
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