Abstract
A lightly biodegraded crude oil from the Tolkinsk field (Upper Jurassic), situated in north-west Siberia, was found to contain a series of C28–C39 isoprenoid alkanes. Most of these components contain a pristane unit linked head-to-head with other isoprenoid units. The structures of these components were elucidated by mass spectral interpretations, comparisons with a synthesised standard and by reference to data published previously in the literature. These results extend the carbon number range, the variety of structural types, and the number of reported occurrences of these compounds in geological samples. These results provide further evidence for a contribution of bacterial cell-wall lipids to crude oils.
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