Abstract

Treatment of OsH3Cl(PPh3)3 in benzene with excess CH3C⋮CPh produced cis-CH3CHCHPh and the novel complex OsCl(C(CH3)CHPh)(CH2CCHPh)(PPh3)2, which contains a β-agostic vinyl ligand and a phenylallene ligand. The structure of the latter unusual complex has been confirmed by a single-crystal X-ray diffraction study.

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