Abstract
Ion-molecular interactions in the HCl−BuiOH system with different compositions (from neat isobutyl alcohol to 37 mol.% HCl) were studied by Multiple Attenuated Total Reflectance (MATR) IR spectroscopy at 30 °C. Proton disolvates (Bui(H)O…H…O(H)Bui)+ with strong symmetrical H bonds are formed upon the addition of HCl to BuiOH. At high concentrations of HCl (C 0 HCl>33 mol.%), (Cl…H…Cl)− ions are formed along with (BuiOH)2H+. The spectra of positively and negatively charged proton disolvates were compared to those of similar ions in the HCl−PriOH and HCl−MeOH systems.
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