Abstract

The presentation will systematize some data concerning rearrangements of fluoroaliphatic compounds catalyzed by Lewis acids or related compounds. Driving forces of these processes can be various factors, such as: 1. thermodynamic instability of systems containing fluorine atoms at sp 2- hybridized carbon atoms; 2. mobility of fluorine atoms in allylic or benzylic position (σ, π-conjugation); 3. activity of fluorine atoms at α-position to heteroatoms bearing an unshared electron pair (p, π-conjugation); 4. energy gain of stable ions formation (allylic cations, stable complex counterions - SbF 6 −, BF 4 − etc.)

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.