Abstract
This paper describes the author's recent work on the preparation and properties of thermally stable ionic liquids (ILs) containing siloxane frameworks. Quaternary ammonium and imidazolium salt-type ILs containing random oligosilsesquioxane frameworks were successfully prepared via the hydrolytic condensation of the corresponding organotrialkoxysilanes by using an aqueous superacid bis(trifluoromethanesulfonyl)imide (HNTf2 ) solution as a catalyst and solvent. Imidazolium salt-type ILs containing polyhedral oligomeric silsesquioxane (POSS) frameworks were also prepared through a reaction similar to that described above by using a water/methanol mixed solution of HNTf2 . In addition, amorphous POSSs with two types of ionic groups randomly distributed in the side chain were prepared. These POSSs were ILs exhibiting fluidity at relatively low temperatures. Furthermore, imidazolium and ammonium salt-type ILs containing cyclic oligosiloxane frameworks were prepared through a reaction similar to that of the corresponding organodialkoxysilanes. The thermal decomposition temperatures of the above ILs containing siloxane frameworks were higher than those of general ILs.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
