Abstract
Gefangen und doch mobil: Ein zentrales PH2−-Ion (siehe Bild; magenta) ist in einem Behälter von zwölf tert-Butoxidanionen (rot und schwarz) in ikosaedrischer Anordnung verkapselt. Die 12 oder 13 Natriumgegenionen sind dynamisch über die 20 Ecken eines regulären Dodekaeders (blau) fehlgeordnet. Die Aktivierungsbarrieren für den Natriumaustausch sind bemerkenswert niedrig (10–30 kJ mol−1) und liegen im Bereich schneller Lithiumionenleiter. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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