Abstract
At room temperature, a new compound with formula (C6H10(NH3)2)2[CoCl4]Cl2·H2O is successfully synthesized by slow evaporation technique. Then, it is characterized by X-ray diffraction to found that it crystallize in the monoclinic system, P21/c space group. The structure can be described by the alternation of organic and inorganic groups form a periodic 0-D network along the a axis. Hydrogen bonds have a crucial role in structure cohesion. In addition, this compound is characterized by infrared and Raman spectroscopy (FT-IR and FT-Raman), TG-DTG-DSC measurements in order to analyze the thermal behavior of the crystal and Hirshfeld surface (HS) analysis. The dielectric study was reported and reveals a good agreement with thermal measurements. Nyquist plots show a non-Debye type relaxation process and confirm that the complex impedance curves follow the Cole Cole law and the conductivity is assured by a hopping mechanism of H+ proton. The optical properties of the crystal were studied using optical absorption UV-visible and photoluminescence (PL) spectroscopy.
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