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Abstract
Cinnamic acid (CA) is a widely distributed metabolite in plant species and is a precursor of many important plant molecules such as lignin and flavonoids. CA exists as both trans and cis isomers; the trans isomer is more common in nature. Previous reports have revealed that the cis isomer of CA (cis-CA) has auxin-like activity when exogenously applied. Moreover, cis-CA was found as the endogenous compound in planta. Here, we report the chemical synthesis of stable-isotope-labeled trans- and cis-CA. Using these labeled compounds as internal standards, we developed a quantification method of CA using LC-MS/MS. We identified cis-CA in diverse plant species, including liverwort, moss, and lycophyte implying an important role of cis-CA in the terrestrial plant kingdom.
Published Version
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