Abstract
AbstractN‐arylthiophene‐2‐carboxamidoxime derivatives (a‐e) were synthesized by using two methods and then subjected to thermolysis at 200–250 °C for 2 h under nitrogen atmosphere either alone or in the presence of tetralin and/or naphthalene as radical scavengers yielded imidazole, oxazole, triazine and amide derivatives. The pyrolysates from both reactions were separated with their constituents by column chromatography and analyzed then identified 1H NMR, 13C NMR and GC‐MS. A plausible mechanism is suggested through two competitive pathways involving the homolysis of N‐O and/or C‐N bonds to account for the thermolysis products.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
