Investigation of the structural evolution and catalytic performance of the CuZnAl catalysts in the hydrogenation of dimethyl oxalate to ethylene glycol

Abstract

A series of CuZnAl catalysts are synthesized and investigated to study the catalytic performance in the gas-phase hydrogenation of dimethyl oxalate to ethylene glycol. The catalytic activity increases with the increasing of the copper loading, but much higher copper content in the catalysts will lead to the aggregation of the copper particles and cause the deactivation of the catalysts. The influence of calcination temperature is also investigated to probe the microstructure evolution of the catalysts. The catalysts calcinated at low temperature display weak metal-support interaction with poor reducibility and exhibit poor catalytic activity. When the calcination temperature was risen up to temperature higher than 873K, the mesoporous structure of the support is collapsed or sintered which further lead to the low dispersion of the copper species and poor catalytic property. The catalyst with molar ratio of copper: zinc: aluminium as 1/4/5 (CZA1-4-5) calcinated at 773K shows the best catalytic performance and can keep the high activity for more than 200h of time on stream, both the conversion and the selectivity to EG still remain unchanged.