Investigation of the structural and phase state of detonation multilayer coatings based on NiCr/NiCr–Al2O3/Al2O3 during high-temperature oxidation

Abstract

This paper presents a study of the structural and phase state of detonation multilayer coatings under hightemperature oxidation. The experiment aimed to find out the effect of high temperatures on the structuralphase state of coatings and their effectiveness in preventing oxidative processes. As a result of the research, it was found that after high-temperature tests, protective phases such as NiCr2O4, Al2O3, and Cr2O3 are formed in the structure of multilayer coatings. These phases were identified to play a key role in preventing intensive oxidation of the metal surface. It was determined that NiCr2O4 provides stability to the metal layer, and Al2O3 and Cr2O3 are effective barriers protecting the surface from aggressive environmental influences. It is important to note that no signs of fracture or detachment were found in the multilayer coatings during the entire experiment. After the first cycle, the uncoated sample experienced peeling of its oxide film, resulting in a significant loss of mass. It was determined that the uncoated steel experiences significantly higher mass loss, indicating a faster formation of oxides on its surface. The experimental data confirm the effectiveness of coatings in protecting against oxidative processes at high temperatures, thereby maintaining the stability and durability of the material under extreme thermal influences.