Abstract
Poly-(p-phenylene) has been obtained in electrochemical oxidation of benzene in the BuPyClAlCl 3 melt. The conductivity of the fresh film is 10–100 S/cm. Even when the film is stored in the dry inert atmosphere, its conductivity reduces. Poly-(p-phenylene) has been also obtained in electrooxidation of benzene with oleum or P 2O 5. Electrochemical properties and IR and ESR spectra have been investigated. The SEM data on the film morphology have been also discussed.
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