Abstract

Poly( p-phenylene) has been obtained by electrochemical oxidation of benzene in a BuPyClAlCl 3 melt. The conductivity of the fresh film is 10 – 100 S/cm. Even when the film is stored in a dry inert atmosphere, its conductivity is reduced. Electrochemical properties and IR and ESR spectra have been investigated. The polymer has an average chain length of 29 – 30 units.

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