Abstract

A comprehensive analysis of invariant phase equilibria involving two, three, and four liquid phases in condensed ternary systems at a fixed pressure is carried out. Every system can be imaged by a tetravalent vertex of the oriented graph of the liquidus surface with edges labeled by three-phase assemblage symbols. The orientation of the edges incident to this vertex makes it possible to recognize the phases vanishing or appearing as a result of the reaction, that is, to determine the reaction equation. The versions under consideration are applicable to describe subsolidus invariant reactions provided that they involve solid exsolution.

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