Abstract
Previously studied disubstituted 4,13-diaza-18-crown-6 derivatives, R<N18N>R, in which the substituents were cyanomethyl or propargyl did not show intramolecular, lariat-type cation solvation. The ring-bound cation in the propargyl derivative is solvated by the six macroring heteroatoms and apically by a bifurcated interaction of the type F⋯K +⋯F. In contrast, when the sidearm is cyanoethyl, an extended intermolecular network forms when the bound cation is either Na + or K +.
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