Abstract
The experimental ionization constants were used to calculate and analyze the effective short-range potential dij for HCl, HBr, and HI in n-alcohols from methanol to octanol at 5–55°C. Changes in the dij and ΔijG* = NAdij values depending on temperature, solvent, and anions were explained in terms of the Samoilov concept of short-range solvation. The character of changes in ΔijG* was shown to be determined by the ratio between the contributions of ion-molecular and intermolecular non-Coulomb interactions, which were, in turn, determined by the structural state of the solvent and solvation of electrolyte particles in solutions of hydrogen halides.
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