Abstract

A series of novel luminescence phosphors Ca9La(PO4)5(SiO4)Cl2:xEu2+ (CLPSCl:Eu2+) with apatite structure have been synthesized by a high temperature solid-state reaction. The phased purity of as-prepared phosphors was verified through XRD technique. For further discussion, a series of analysis were performed such as the photoluminescence emission and excitation spectrum and decay lifetime to identify the luminescent properties of CLPSCl:Eu2+ phosphors. The CLPSCl:Eu2+ displays broad excitation spectra ranging from 250 to 450 nm, and intends emission intensity at 461 nm under 345 nm. The optimum Eu2+ concentration of CLPSCl is 8 mol%. The luminescence decay lifetime of the optimum phosphors was measured to be 275 ns. All of the results obtained highly indicate that CLPSCl:Eu2+ is potentially blue-emitting phosphor for application in white LEDs.

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