Inside Back Cover: Combinatorial Self‐Assembly of Coordination Cages with Systematically Fine‐Tuned Cavities for Efficient Co‐Encapsulation and Catalysis (Angew. Chem. Int. Ed. 33/2022)

Abstract

A combinatorial self-assembly approach with enPd(NO3)2 and three different ligands is demonstrated by Li-Xuan Cai, Qihui Chen, Qing-Fu Sun, and co-workers in their Research Article (e202204732). The controllable arrangement of different ligands not only gives rise to a family of six different palladium–organic cages with systematically varied shapes and cavities, but also leads to emergent host–guest chemistry of the heteroleptic cages due to the fusion of two half cavities from their parent homoleptic cages.