Inorganic nanomaterials in polymeric water decontamination membranes

Polymer-matrix nanocomposite membranes for water treatment

Both brackish water desalination and seawater desalination processes are well established and in common use around the globe to create new water supply sources. The farther the location of the source water from the ocean or seashore, the lower the salinity (TDS) of the water and the lower the osmotic pressure that needs to be overcome when desalinated water is produced. This is one of the major reasons that brackish desalination is often considered less costly than seawater desalination. A number of project considerations, however, indicate that seawater desalination can be beneficial and more cost-effective than brackish water desalination. To make a fair comparison, we need to properly compare all major aspects of both types of projects to define the best and most appropriate desalination technology. While brackish water has less feed water TDS, it is more challenging to dispose of the produced concentrate. Also, although brackish water desalination needs less energy to overcome osmotic pressure, it usually requires more energy to draw the water from the well than it takes to pump seawater from the open ocean intake. Another factor is that the temperature of the brackish well water may be lower than the temperature of ocean water, giving seawater desalination an advantage in energy demand. In comparing brackish to seawater desalination, these major aspects should be evaluated: (1) Locations of seawater and brackish water plants, relative to the major consumers of the desalinated water, (2) Transportation (pumping and disposal) costs of the feed water and produced water, (3) Potential colocation of a seawater plant with a large industrial user (e.g., power plant) of the seawater for cooling or other purposes, (4) Produced quality of brackish water and seawater desalination in terms of major minerals and emerging contaminants, (5) Sustainability of the water source: capacity and depth of the brackish water wells, as well as the type of soil. (6) Technical and economic aspects of produced concentrate disposal, (7) Permitting process costs for brackish and seawater desalination, and (8) The economics of both brackish and seawater desalination treatment processes: capital costs, operational and maintenance (O&M) costs, lifetime water cost, and total water cost (TWC). This paper discusses the major evaluation criteria and considerations involved in properly comparing the economic and technical aspects of brackish and seawater desalination to determine the more favorable desalination technology for a given desalination project.

The utilization of chitin and chitosan as green modifiers in nanocomposite membrane for water treatment

برای بررسی اثر سطوح شوری آب آبیاری و زمان شروع آبیاری با آب شور و لب‌شور بر خصوصیات کمی خربزه دیررس، آزمایشی با 7 تیمار و 3 تکرار در قالب بلوک‌های کامل تصادفی با استفاده از روش آبیاری قطره‌ای نواری، در مرکز تحقیقات کشاورزی و منابع طبیعی خراسان رضوی انجام شد. تیمارهای آبیاری عبارت بودند از: 1- آبیاری با آب شیرین (6/0 دسی‌زیمنس بر متر) از ابتدای کاشت تا انتهای فصل برداشت، 2- آبیاری با آب با شوری 3 دسی‌زیمنس برمتر از ابتدا تا انتهای فصل داشت، 3-آبیاری با آب با شوری 6 دسی‌زیمنس بر متر از ابتدا تا انتهای فصل، 4- آبیاری با آب با شوری 6 دسی‌زیمنس بر متر از 20 روز بعد از جوانه‌زنی تا انتها، 5- آبیاری با آب با شوری 3 دسی‌زیمنس بر متر از 20 روز بعد از جوانه‌زنی تا انتها، 6- آبیاری با آب با شوری 6 دسی‌زیمنس بر متر از 40 روز بعد از جوانه‌زنی تا انتها و 7- آبیاری با آب با شوری 3 دسی زیمنس بر متر از 40 روز بعد از جوانه‌زنی تا انتهای فصل داشت. نتایج نشان داد که، شوری آب بر عملکرد کل، عملکرد اقتصادی و کارآیی مصرف آب آبیاری تاثیر معنی‌داری داشت. بالاترین عملکرد کل و عملکرد اقتصادی و کارآیی مصرف آب آبیاری از تیمار شاهد بدست آمد که تفاوت آن‌ها با تیمارهای آب شور و لب‌شور معنی‌دار بود. در ضمن تفاوت بین عملکردهای تیمارهای شور و لب‌شور معنی‌دار نبودند. آبیاری با آب شیرین در اوایل دوره رشد باعث افزایش محصول نشده بلکه، باعث وارد شدن تنش بیشتر به گیاه می‌شود.

Unveiling the spatiotemporal dynamics of membrane fouling: A focused review on dynamic fouling characterization techniques and future perspectives

To secure existing water resources is one of the imposing challenges to attain sustainability and ecofriendly world. Subsequently, several advanced technologies have been developed for water treatment. The most successful methodology considered so far is the development of water filtration membranes for desalination, ion permeation, and microbes handling. Various types of membranes have been industrialized including nanofiltration, microfiltration, reverse osmosis, and ultrafiltration membranes. Among polymeric nanocomposites, nanocarbon (fullerene, graphene, and carbon nanotubes)-reinforced nanomaterials have gained research attention owing to notable properties/applications. Here, fullerene has gained important stance amid carbonaceous nanofillers due to zero dimensionality, high surface areas, and exceptional physical properties such as optical, electrical, thermal, mechanical, and other characteristics. Accordingly, a very important application of polymer/fullerene C60 nanocomposites has been observed in the membrane sector. This review is basically focused on talented applications of polymer/fullerene nanocomposite membranes in water treatment. The polymer/fullerene nanostructures bring about numerous revolutions in the field of high-performance membranes because of better permeation, water flux, selectivity, and separation performance. The purpose of this pioneering review is to highlight and summarize current advances in the field of water purification/treatment using polymer and fullerene-based nanocomposite membranes. Particular emphasis is placed on the development of fullerene embedded into a variety of polymer membranes (Nafion, polysulfone, polyamide, polystyrene, etc.) and effects on the enhanced properties and performance of the resulting water treatment membranes. Polymer/fullerene nanocomposite membranes have been developed using solution casting, phase inversion, electrospinning, solid phase synthesis, and other facile methods. The structural diversity of polymer/fullerene nanocomposites facilitates membrane separation processes, especially for valuable or toxic metal ions, salts, and microorganisms. Current challenges and opportunities for future research have also been discussed. Future research on these innovative membrane materials may overwhelm design and performance-related challenging factors.

Brackish water is a potential fresh water resource with lower salt content than seawater. Desalination of brackish water is an important option to alleviate the prevalent water crisis around the world. As a membrane technology ranging between UF and RO, NF can achieve the partial desalination via size exclusion and charge exclusion. So, it has been widely concerned and applied in treatment of brackish water during the past several decades. Hereon, an overview of the progress in research on and application of NF technology for brackish water treatment is provided. On the basis of expounding the features of brackish water, the factors affecting NF efficiency, including the feed water characteristics, operating conditions and NF membrane properties, are analyzed. For the ubiquitous membrane fouling problem, three preventive fouling control strategies including feed water pretreatment, optimization of operating conditions and selection of anti-fouling membranes are summarized. In addition, membrane cleaning methods for restoring the fouled membrane are discussed. Furthermore, the combined utilization of NF with other membrane technologies is reviewed. Finally, future research prospects are proposed to deal with the current existing problems. Lessons gained from this review are expected to promote the sustainable development of brackish water treatment with NF technology.

Desalination of seawater and brackish water with reverse osmosis and the disc tube module DT

During last few decades, membrane technology has emerged as an efficient technique over conventional methods due to its high removal capacity, ease in operation and cost effectiveness for wastewater treatment and production of clean water. Membrane based separations are commonly based on polymeric membranes because of their higher flexibility, easily pore forming mechanism, low cost and smaller space for installation as compared to inorganic membranes. Commonly employed membrane fabrication phase inversion method has been shortly reviewed in this article. Major limitation of membrane based separations is fouling and polymeric membranes being hydrophobic in nature are more prone to fouling. Fouling is a deposition of various colloidal particles, macromolecules (polysaccharides, proteins), salts etc. on membrane surface and within pores thus impedes membrane performance, reduces flux and results in high cost. Modification of polymeric membranes due to its tailoring ability with nanomaterials such as metal based and carbon based results in polymeric nano-composite membranes with high antifouling characteristics. Nanomaterials impart high selectivity, permeability, hydrophilicity, thermal stability, mechanical strength, and antibacterial properties to polymeric membranes via blending, coating etc. modification methods. Characterization techniques has also discussed in later section for studying morphological properties and performance of polymer nano-composite membranes. Graphical Abstract

Fabrication of polymeric nanocomposite forward osmosis membranes for water desalination—A review

Desalination of brackish water by nanofiltration and reverse osmosis

In recent years, there has been growing interest in using polymer nanocomposite membranes as a more advanced method for removing pollutants from water and treating wastewater for various purposes. In this study, thin‐film nanocomposite (TFN) membranes of polycarbonate/polyvinyl alcohol–titanium dioxide thin‐film (PC/PVA–TiO2) were fabricated by dip‐coating a PC substrate in a PVA/TiO2 solution. Various methods, including attenuated total reflectance‐Fourier transform infrared (ATR‐FTIR) spectroscopy, field emission scanning electron microscopy (FE‐SEM), atomic force microscopy (AFM), and water contact angle were utilized to assess the structural characteristics of the produced membranes. The PC/PVA thin‐film composite (TFC) and PC/PVA–TiO2 TFN membranes were then examined in a submerged membrane system to evaluate their effectiveness in filtering humic acid (HA) under various vacuum transmembrane pressure (0.3 and 0.6 bar) condition. The FTIR‐ATR results confirmed the formation of the active layer of PVA/TiO2 nanoparticles (NPs). It was observed that adding 1 wt.% of TiO2 NPs to the active layer of PVA/TiO2 significantly enhanced the water contact angle from 77.5° for PC support to 55.3° for PC/PVA–TiO2 (0.1) TFN membranes. Furthermore, the FE‐SEM results confirmed the formation of an active layer of PVA/TiO2 with a thickness of 237.87 nm. The pure water flux increased from 101.64 L/m2h for the PC/PVA TFC membrane to 144.02 L/m2h and 199.09 L/m2h for the PC/PVA–TiO2 (0.05) and PC/PVA–TiO2 (0.1) TFN membranes, respectively. Also, the results revealed that at lower transmembrane pressure, all membranes showed higher value in HA removal as compared to when higher transmembrane pressure was used.

Chapter 11 - Prospects of nanocomposite membranes for water treatment by osmotic-driven membrane processes

Reverse osmosis (RO) membrane technology is considered to be the premier process used for the purpose of seawater and brackish water desalination and water treatment of municipal and industrial wastewater for water reclamation and reuse. Membrane biofouling is a significant challenge in RO processes due to the interference of biofilm formed on the membrane surface on membrane performance. Thus, diverse areas of research are geared towards the understanding, prevention, and control of biofouling. Diagnosis of biofouling is difficult since no single microbial assay on the source water can accurately predict biofouling during the RO process. Biofouling evaluation methods of fouled membranes and collected biofoulants from the treatment processes are counterproductive when biofouling prevention is warranted. It is therefore important for the detection tests to be predictive enough taking into consideration the water quality characteristics of the source feed water, the properties of the RO membrane used for the water treatment, and the hydrodynamic properties during the RO process. This chapter provides an overview of biofouling tests most commonly used for detection of biofouling in the source feed water, and in the foulants and fouled membranes. It has a brief section on the use of flow cell units that can simulate hydrodynamic conditions in the RO plant with the ability to predict biofouling.

The role of desalination in bridging the water gap in Jordan