Innovative utilization of molecular imprinting technology for selective adsorption and (photo)catalytic eradication of organic pollutants

Abstract

The rapid development of industrialization and urbanization results in a numerous production of various organic chemicals to meet the increasing demand in high-quality life. During the synthesis and utilization of these chemical products, their residues unavoidably emerged in environments to severely threaten human’s health. It is thus urgent to exploit effective technology for readily removing the organic pollutants with high selectivity and good reusability. As one of the most promising approaches, molecular imprinting technology (MIT) employs a chemically synthetic route to construct artificial recognition sites in highly-crosslinked matrix with complementary cavity and functional groups to target species, which have been attracting more and more interest for environmental remediation, such as the selective adsorption/separation and improved catalytic degradation of pollutants. In this review, MIT is first introduced briefly to understand their preparing process, recognition mechanism and common imprinted systems. Then, their specific binding affinities are demonstrated for selectively adsorbing and removing target molecules with a large capacity. Furthermore, the innovative utilization of MIT in catalytic eradication of pollutants is comprehensively overviewed to emphasize their enhanced efficiency and improved performances, which are classified by the used catalytically-active nanocrystals and imprinted systems. After summarizing recent advances in these fields, some limitations are discussed and possible suggestions are given to guide the future exploitation on MIT for environmental protection.