Abstract
The infrared spectra of CH 3HgCl, CH 3HgBr, and CH 3HgI in the gaseous phase have been recorded between 4000 and 400 cm −1. The CH stretching bands at 3000 cm −1 and the CH 3 rocking bands in the range 900–700 cm −1 have been examined under high resolution and the rotational substructures ( Q subbranches in perpendicular bands) resolved allowing, in the cases of rocking bands, the assignment of the rotational number K. For the Coriolis zeta constants of chloride, bromide, and iodide the following values were obtained, respectively: 0.07, 0.08, 0.06 for ζ 5, and 0.23, 0.22 2 and 0.23 7 for ζ 7.
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