Abstract

The infrared spectra of various carbohydrates in water have been recorded and found to be characteristic of each compound. Infrared techniques have been used to determine mutarotation constants of α- d-glucose, β- d-glucose and β- d-mannose. Absorbance values at a constant characteristic wavelength were observed as they changed with time; and were applied in an equation previously used in polarimetric determinations of the mutarotation constants. The mutarotation constants determined by the infrared method were in good agreement with those determined polarimetrically.

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