Abstract
The compound, triallyl-1,3,5-triazine-2,4,6-(1 H,3 H,5 H)trione (T 3ONE) has apparent D 3 h symmetry, and forms hydrogen bonded complexes when in CHCl 3-CCl 4 solvent systems. The IR active ν oop(CO) 3, E′ mode for T 3ONE correlates in a pseudo linear manner with the solvent acceptor number ( AN). The AN values for methyl alcohol, ethyl alcohol, isopropyl alcohol, and tert-butyl alcohol correlate only with the ν oop(CO) 3 frequencies for T 3ONE molecules which are intermolecularly hydrogen bonded. The AN values for these four alkyl alcohols are significantly less when T 3ONE is in solution with ▪ and the CO groups are not intermoelcularly hydrogen bonded. Due to steric and geometric factors between the solute and solvent, the AN values are not a precise measure of the strength of the solute-solvent interaction.
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