Abstract

CO2 capture and storage (CCS) is an important technology for avoiding atmospheric CO2 emissions, which are principally originated from fossil fuels combustion. Anthropogenic CO2 contains impurities that can strongly modify the properties of the stream. Several authors have shown that some of these impurities, such as SO2 present in emissions from sulfur-containing fuels, could be favorable for some steps of the process, and the possibility of cocapture has been proposed. To assess this possibility with regard to the transport stage of CCS, we determined the influence of SO2 on selected parameters of transport by pipeline (minimal operational pressure, pressure and density drops, distance between boosters, booster power, and inner diameter of the pipeline, and the Joule-Thomson coefficient). For this purpose, we obtained new and accurate experimental data for the density and vapor–liquid equilibrium of five CO2 + SO2 mixtures under conditions of interest for CCS and speed of sound data for four of them. We...

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