Abstract
Water contamination by ammonium (NH4+) can present considerable risks to natural ecosystems. This work evaluates the potential application of biochar, produced from the pyrolysis of digested sludge, to remove ammonium from water. Anaerobic digester sludge was collected from a municipal wastewater treatment plant in Alberta, Canada, and individual biochars were produced at 50 °C temperature increments between 350 °C and 550 °C. The chemical characteristics of the resulting biochars were determined using elemental analysis, scanning electron microscopy (SEM), BET surface area analysis, and Fourier transform infrared spectroscopy (FTIR). Our findings demonstrate that the biochar yield decreased with increasing pyrolysis temperature, and biochar produced at 450 °C (BC450) had the highest ammonium removal capacity due to its higher surface area and functional group density. The Langmuir isotherm best described the observed ammonium removal capacity by the biochars, indicating that monolayer chemical adsorption may be the dominating mechanism. Biochar ammonium removal capacity was 1.2 mg NH4N per gram of biochar in municipal wastewater, which is lower than that observed in parallel experiments using a synthetic ammonium solution (1.4 mg NH4+-N/g biochar). This phenomenon is likely due to competition between ammonia and other containments for sorption to biochar surface sites. Our results demonstrate for the first time ever that biochar produced from digester sludge is a promising adsorbent for ammonium removal from municipal wastewater.
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