Influence of particle size distribution on the analysis of pellets of plant materials by laser-induced breakdown spectroscopy

Abstract

Pellets of sieved plant materials (150, 106, 75, 53 and 20μm sieve apertures) were prepared and analyzed by laser-induced breakdown spectroscopy (LIBS), and the results for Ca, K, Mg, P, B and Mn were discussed as a function of particle size distribution. This parameter is of key importance for appropriate test sample presentation in the form of pressed pellets for quantitative analysis by LIBS. Experiments were carried out with a Q-switched Nd:YAG laser at 1064nm, and a spectrometer with Echelle optics and an intensified charge-coupled device. Results indicated that smaller particles yielded up to 50% emission signal intensities' enhancement and attained better measurements' precision (site-to-site variation). Moreover, matrix effects were reduced by analyzing pellets prepared from <75μm sieved fractions (mean particle size=32μm; d95=102μm) and by using a 50Jcm−2 laser fluence (220mJ per pulse; 750μm laser spot size). The preparation of pellets from laboratory samples with monomodal particle size distributions, where most particles were smaller than 100μm, was decisive for improving analyte micro-homogeneity within the test samples and for attaining lower coefficients of variation of measurements, typically lower than 10% (n=10 sites per pellet; 20 laser pulses per site).