Influence of Er3+ ions on the physical, structural, optical, and thermal properties of ZnO–Li2O–P2O5 glasses

Abstract

Er3+ doped zinc lithium phosphate glass samples were synthesized by the very simple melt quenching method. The obtained X-ray diffraction patterns specify that the prepared glass samples exhibit glassy nature. The physical properties like packing density, molar volume, density, oxygen packing density, interionic distance, field strength, rare earth ion concentration, and polaron radius were calculated using appropriate formulae. DTA curve was analysed to evaluate the crystallization temperature, melting temperature, and glass transition temperature and hence study the thermal properties. Fourier transform infrared spectrum was recorded to examine the functional groups in the glass and study the structural characteristics of the glass. It showed the presence of symmetrical and asymmetrical stretching vibration modes of P–O–P linkages, bending modes of P–O in PO4, bending and stretching vibrations of OH groups and P–O–H water absorbance in the glasses. The absorption spectra of the prepared glasses in the UV–visible region (wavelength 200–1100 nm) were taken to study the optical properties of the glasses. The urbach energy and optical energy bandgap values are determined using Davis–Mott method. The refractive index of all the prepared glass samples is also measured and these values are used to determine the corresponding molar refraction, the molecular polarizability of oxide ions, dielectric constant, reflection loss, metallization criterion, electronic polarizability of the oxide ions, interaction parameter, electronegativity, optical basicity, and electric susceptibility of all the glass samples using appropriate formulae.