Abstract
The specific retention volumes of n-decane on 24 liquid stationary phases of the silicone type were calculated from the retention indices of the samples used by McReynolds in his characterization of gas chromatographic stationary phases. The average error of prediction was 2.24%. The effects of errors on the logarithm of the relative retentions of consecutive n-alkanes and the values of the retention indices were studied, and also its dependence on stationary phase polarity.
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